(μ-Naphthalene-1,5-disulfonato-κ2 O 1:O 5)bis[triaqua(glycinato-κ2 N,O)copper(II)]
نویسندگان
چکیده
In the title compound, [Cu(2)(C(2)H(4)NO(2))(2)(C(10)H(6)O(6)S(2))(H(2)O)(6)], the naphthalene-disulfonate group lies on a center of inversion and bridges two glycinate-chelated Cu(II) atoms. The Cu(II) atom exists in a CuNO(4) square-pyramidal geometry that is distorted towards an octa-hedron owing to a long Cu-O(sulfonate) bond [2.636 (2) Å]. In the crystal, extensive N-H⋯O and O-H⋯O hydrogen bonds link adjacent mol-ecules into a three-dimensional network.
منابع مشابه
catena-Poly[[[bis(1,10-phenanthroline-κ2 N,N′)manganese(II)]-μ-9,10-dioxoanthracene-1,5-disulfonato-κ2 O 1:O 5] tetrahydrate]
The title complex, {[Mn(C(14)H(6)O(8)S(2))(C(12)H(8)N(2))(2)]·4H(2)O}(n), exhibits a chain-like polymeric structure with 9,10-dioxo-anthracene-1,5-disulfonate anions bridging Mn(II) atoms in a bis-monodentate mode. The unique Mn(II) atom is located on a crystallographic centre of inversion. Four N atoms from two chelating 1,10-phenanthroline ligands and two sulfonate O atoms from two symmetry-r...
متن کاملcatena-Poly[[bis(2,2′-bipyridine-κ2 N,N′)cadmium(II)]-μ-9,10-dioxoanthracene-1,5-disulfonato-κ2 O 1:O 5]
The title complex, [Cd(C(14)H(6)O(8)S(2))(C(10)H(8)N(2))(2)](n), exhibits a chain-like polymeric structure with 9,10-dioxoanthracene-1,5-disulfonate anions bridging Cd(II) atoms in a bis-monodentate mode. The Cd(II) atom shows a distorted octa-hedral environment, with four N atoms from two chelating 2,2'-bipyridine ligands forming the equatorial plane and two sulfonate O atoms from two 9,10-dio...
متن کاملBis[triaqua(1H-1,2,4-triazole-3,5-dicarboxylato-κ2 O 3,N 4)copper(II)] di-μ-aqua-bis[diaqua(1H-1,2,4-triazole-3,5-dicarboxylato-κ2 O 3,N 4)copper(II)]
In the title compound, [Cu(C(4)HN(3)O(4))(H(2)O)(3)](2)[Cu(2)(C(4)HN(3)O(4))(2)(H(2)O)(6)], both monomeric and dimeric mol-ecules are present in the solid state. In the monomeric compound, the Cu(II) atom is five-coordinated in a square-pyramidal configuration by one O atom and one N atom from one 1H-1,2,4-triazole-3,5-dicarboxyl-ate (TZDCA(2-)) ligand and three O atoms from water mol-ecules. I...
متن کاملcatena-Poly[[[diaquacopper(II)]-bis[μ-1,5-bis(1H-imidazol-1-yl)pentane-κ2 N 3:N 3′]] naphthalene-1,5-disulfonate]
In the title complex, {[Cu(C11H16N4)2(H2O)2](C10H6O6S2)} n , the Cu(II) atom, lying on an inversion center, is six-coordinated by two water mol-ecules and four N atoms from four 1,5-bis-(1H-imidazol-1-yl)pentane (biim-5) ligands in a distorted octa-hedral geometry. Adjacent Cu(II) atoms are linked by two biim-5 ligands, forming a chain along [111]. Two atoms of the pentane group are disordered ...
متن کاملDi-μ-aqua-bis(μ-pyridazine-4-carboxylato-κ2 N:N′)bis[triaqua(pyridazine-4-carboxylato-κ2 O,O′)lead(II)] dihydrate
The structure of the title compound, [Pb(2)(C(5)H(3)N(2)O(2))(4)(H(2)O)(6)]·2H(2)O, is composed of dimeric mol-ecules in which two symmetry-related Pb(2+) ions are bridged by a pair of two pyridazine-4-carboxyl-ate ligand mol-ecules via both heterocyclic N atoms and two water O atoms. Each Pb(2+) ion is also coordinated by two carboxyl-ate O atoms and three water O atoms, leading to a highly ir...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره 68 شماره
صفحات -
تاریخ انتشار 2012